非水溶剂热法制备(001)面暴露的F/TiO_2纳米晶及其光催化活性  

Synthesis and Photocatalytic Activity of F/TiO_2 Nanocrystals with Exposed(001) Facets via a Nonhydrolytic Solvothermal Route

作　　者：蔡陈灵[1] 王金果[1] 曹锋雷[1] 李和兴[1] 朱建[1] 

机构地区：[1]上海师范大学化学系,上海200234

出　　处：《催化学报》2011年第5期862-871,共10页

基　　金：国家自然科学基金(20825724;20907032);上海市项目(0952nm00500;09520715300;07dz22303;10QA1405300;S30406;10YZ69)~~

摘　　要：采用非水体系溶剂热法制备了(001)面暴露的锐钛矿相F/TiO2纳米光催化剂.结果表明,F的掺杂对TiO2纳米单晶的形成影响很大.一方面,F离子作为晶面导向剂稳定(001)晶面,形成(001)面暴露的锐钛矿相TiO2;另一方面,F离子也起到稳定剂作用,抑制纳米粒子的快速生长.以光催化降解甲基橙为模型反应比较了不同F/TiO2样品和商业P25样品的光催化活性.同时,通过选用不同捕获剂,研究了F/TiO2和P25样品在甲基橙降解反应中的活性物种.F/TiO2 nanocrystals with exposed（001）facets were synthesized by a nonhydrolytic solvothermal route.The influence of F ions on the formation process was investigated in detail.The F ions function as a crystal-face directing agent and a stabilizing agent.The photocatalytic activities of the F/TiO2 and commercial P25 samples were determined by the degradation of methyl orange.The influencing factors and active species in the degradation process are discussed after particular characterization and experiments with different scavengers.

关 键 词：氟掺杂 二氧化钛 光催化 (001)晶面 甲基橙 

分 类 号：O643.36[理学—物理化学]