CRYSTALLIZATION BEHAVIOR OF POLYLACTIDE ON HIGHLY ORIENTED POLYETHYLENE THIN FILMS  

作　　者：闫寿科 

机构地区：[1]State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology

出　　处：《Chinese Journal of Polymer Science》2011年第4期513-519,共7页高分子科学（英文版）

基　　金：supported by the National Natural Science Foundations of China(Nos.50833006,20634050 and 50973008);the 47~(th) postdoctoral granted financial support from China Postdoctoral Science Foundation (No.20100470191)

摘　　要：The crystalline structure and morphology of the PLA crystallized isothermally from the glassy state on highly oriented PE substrates at 130℃ were investigated by means of optical microscopy, AFM and X-ray diffraction. The results indicate that the PE substrate influences the crystallization behavior of PLA remarkably, which leads to the growth of PLA crystals on PE substrate always in edge-on form rather than the twisted lamellar crystals from edge-on to flat-on when crystallizing the PLA on glass surface under the same condition. The edge-on PLA lamellae on the PE substrate are preferentially arranged with their long axes in the chain direction of the PE substrate crystals. It is further demonstrated that except for the different crystal orientation, the PE does not influence the crystalline modification and crystallinity of the PLA.The crystalline structure and morphology of the PLA crystallized isothermally from the glassy state on highly oriented PE substrates at 130℃ were investigated by means of optical microscopy, AFM and X-ray diffraction. The results indicate that the PE substrate influences the crystallization behavior of PLA remarkably, which leads to the growth of PLA crystals on PE substrate always in edge-on form rather than the twisted lamellar crystals from edge-on to flat-on when crystallizing the PLA on glass surface under the same condition. The edge-on PLA lamellae on the PE substrate are preferentially arranged with their long axes in the chain direction of the PE substrate crystals. It is further demonstrated that except for the different crystal orientation, the PE does not influence the crystalline modification and crystallinity of the PLA.

关 键 词：POLYETHYLENE Poly（lactide） Induced crystallization MORPHOLOGY Orientation. 

分 类 号：O631.3[理学—高分子化学]