改性HZSM-5分子筛催化合成富马酸二甲酯  

Synthesis of Dimethylfurmarate Catalyzed by Modified HZSM 5 Molecular Sieve

作　　者：吕金魁[1] 李绍武[1] 于景明[1] 李梅彤[1] 

机构地区：[1]天津理工学院

出　　处：《天津理工学院学报》1999年第A05期77-79,共3页Journal of Tianjin Institute of Technology

摘　　要：利用改性ＨＺＳＭ－５分子筛为催化剂、顺丁烯二酸酐与甲醇反应，一步法合成丁烯二酸二甲酯，收率达９０％以上．Dimethylfumarate was synthesized by one step reactien of Maleic anhydride with methanol in the presence of modified HZSM 5. The yield of dimethylfumarate can be obtained over 90%. The influence of reaction conditions such as the mole ratio of anhydride to methanol, the quantity of the catalyst, reaction temperature and reaction time was determined. The catalyst was repeatedly used at least 10 times and, the catalytic activity was not decreased basically.

关 键 词：富马酸二甲酯 改性 HZSM-5 催化 分子筛 

分 类 号：O623.624.2[理学—有机化学]