Preparation and characterization of spherical mesoporous ZrO_(2)-Al_(2)O_(3) composites with high thermal stability  

作　　者：LI Yang FENG JunTing LI DianQing 

机构地区：[1]State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China

出　　处：《Science China Chemistry》2011年第7期1032-1038,共7页中国科学(化学英文版)

基　　金：supported by the National Natural Science Foundation of China;the 111 Project (B07004);the Program for Changjiang Scholars and Innovative Research Teams in Universities (IRT0406)

摘　　要：Spherical mesoporous ZrO_(2)-Al_(2)O_(3) composites containing different zirconia content have been synthesized by an oil-column sol-gel method.A mixed alumina-zirconia hydrosol and hexamethylenetetramine solution were mixed together and added dropwise into a hot oil column.Due to the surface tension,spherical gel particles were formed in the oil column.The spherical gel particles were then aged and washed by deionized water and dried at 120 ℃ for 12 h and then calcined at 600 ℃ for 8 h,960 ℃ for 8 h or 1200 ℃ for 12 h.X-ray diffraction and nitrogen adsorption-desorption measurements indicated that the presence of zirconia prevents the sintering of alumina and the obtained ZrO_(2)-Al_(2)O_(3) composites have much larger surface areas than pure alumina.Temperature-programmed desorption of ammonia results illustrated that the addition of zirconia leads to an increase in the number of strong acid sites and the total number of acid sites compared with pure alumina.Thus,the spherical mesoporous ZrO_(2)-Al_(2)O_(3) composites prepared in this way were shown to be suitable for high temperature catalytic processes as a catalyst support.Spherical mesoporous ZrO_(2)-Al_(2)O_(3) composites containing different zirconia content have been synthesized by an oil-column solgel method. A mixed alumina-zirconia hydrosol and hexamethylenetetramine solution were mixed together and added dropwise into a hot oil column. Due to the surface tension, spherical gel particles were formed in the oil column. The spherical gel particles were then aged and washed by deionized water and dried at 120℃for 12 h and then calcined at 600℃ for 8 h, 960℃ for 8 h or 1200 ℃ for 12 h. X-ray diffraction and nitrogen adsorption-desorption measurements indicated that the presence of zirconia prevents the sintering of alumina and the obtained ZrO_(2)-Al_(2)O_(3) composites have much larger surface areas than pure alumina. Temperature-programmed desorption of ammonia results illustrated that the addition of zirconia leads to an increase in the number of strong acid sites and the total number of acid sites compared with pure alumina. Thus, the spherical mesoporous ZrO_(2)-Al_(2)O_(3) composites prepared in this way were shown to be suitable for high temperature catalytic processes as a catalyst support.

关 键 词：spherical alumina ZrO_(2)-Al_(2)O_(3) composites mesoporous material thermal stability 

分 类 号：O614.412[理学—无机化学]