Synthesis and Crystal Structure of Bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) Perchlorate Hydrate  

作　　者：王乐 边玮玮 朱凌 倪荣军 陶琳 

机构地区：[1]State Key Laboratory of Ceramic,Zibo Entry and Exit Inspection and Quarantine Bureau [2]Department of Medical Chemistry,Weifang Medical University

出　　处：《Chinese Journal of Structural Chemistry》2011年第6期882-886,共5页结构化学（英文）

基　　金：Financially supported from the Science Research Foundation of Shandong Entry-Exit Inspection;Quarantine Bureau (No. SK201042);Weifang Medical University (No. KQ2007030)

摘　　要：The title complex bis（2-acetylpyridine thiosemicarbazonato）-indium（iii） perchlo-rate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide（L） with indium（iii） perchlorate,and its structure was characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal of the title compound（[In（C8H9N4S）2]ClO4·H2O） belongs to monoclinic,space group P21/c with a = 12.6438（18）,b = 12.6259（18）,c = 15.116（2） nm,β = 105.800（2）°,Z = 4,V = 2321.9（6） nm3,Mr = 618.79,Dc = 1.770 g/cm3,μ = 1.359 mm-1,F（000） = 1240,R = 0.0265 and wR = 0.0675.X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules.The title complex bis（2-acetylpyridine thiosemicarbazonato）-indium（iii） perchlo-rate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide（L） with indium（iii） perchlorate,and its structure was characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal of the title compound（[In（C8H9N4S）2]ClO4·H2O） belongs to monoclinic,space group P21/c with a = 12.6438（18）,b = 12.6259（18）,c = 15.116（2） nm,β = 105.800（2）°,Z = 4,V = 2321.9（6） nm3,Mr = 618.79,Dc = 1.770 g/cm3,μ = 1.359 mm-1,F（000） = 1240,R = 0.0265 and wR = 0.0675.X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules.

关 键 词：self-assembly cationic complex polyatomic counterion HYDROGEN-BOND 

分 类 号：O641.4[理学—物理化学]