胶质液体泡沫的制备及其在悬浮床加氢催化剂分散方面的应用  

Preparation of Colloidal Liquid Aphron and Its Application to the Dispersion of Catalysts for Slurry Phase Hydroprocessing

作　　者：廉勇[1,2] 沐宝泉[1] 邓文安[1] 双秀芝[3] 阙国和[1] 

机构地区：[1]中国石油大学重质油国家重点实验室,山东青岛266555 [2]中国石化扬子石油化工有限公司研究院,江苏南京210048 [3]中国海洋大学海洋生命学院,山东青岛266003

出　　处：《石油学报（石油加工）》2011年第3期471-475,共5页Acta Petrolei Sinica(Petroleum Processing Section)

基　　金：教育部创新团队"重质油高效转化的绿色化学与工程"项目资助

摘　　要：根据悬浮床加氢油溶性催化剂与水溶性催化剂的经验配比确定了胶质液体泡沫(CLA)的制备方案,并借助光学显微镜及动态光散射仪等对其结构和性质进行表征。以辽河常压渣油(LHAR)和委内瑞拉常压渣油(VRAR)为原料油,对以CLA方式得到的催化剂复配及分散后油样进行了光学显微镜观察及悬浮床加氢反应评价。与传统的分散方式相比,采用CLA分散催化剂的LHAR油样和VRAR油样的悬浮床加氢反应生焦率分别由1.25%降低至0.98%和由1.31%降低至1.06%,馏分油收率有所提高。The prescription to prepare colloidal liquid aphron（CLA） was determined according to the experiential ratio of oil-soluble and water-soluble catalysts of slurry phase hydro-processing.Structure and stability of CLA were discussed with the help of optical microscopy,dynamic light scattering and so on.Liaohe and Venezuela residual oils（LHAR and VRAR） were taken as base oil to evaluate the dispersion effectiveness of CLA by means of microscope observation and autoclave reaction.Compared with traditional dispersion technology,slurry phase hydro-processing,coke yields of LHAR and VRAR dispersed by CLA reduced from 1.25% to 0.98% and from 1.31% to 1.06%,respectively,with yield of distillates increased to some extent.

关 键 词：悬浮床加氢 催化剂的分散 胶质液体泡沫 辽河常压渣油(LHAR) 委内瑞拉常压渣油(VRAR) 

分 类 号：TE624.4[石油与天然气工程—油气加工工程]