1-癸烯制备润滑油基础油的合成研究  

Study on Synthesis of Lube Base Oil by Oligomerization of 1-Decene

作　　者：马建梅[1] 李惠萍[1] 胡子昭[1] 吴浩[1] 

机构地区：[1]新疆大学化学化工学院,新疆乌鲁木齐830008

出　　处：《当代化工》2011年第6期557-559,564,共4页Contemporary Chemical Industry

摘　　要：以Al(Et)2Cl/TiCl4为催化剂对1-癸烯齐聚制备润滑油基础油的合成实验进行研究。考察了不同主催化剂、催化剂用量、Al/Ti摩尔比、反应时间和反应温度对PAO的影响。结果表明,以Al(Et)2Cl/TiCl4为催化剂在50℃下反应4 h制备PAO是可行的,并且产物收率高,性能优良。Synthesis of lube base oil from 1-decene over Al（Et）2Cl/TiCl4 catalyst was studied.Effect of catalyst type,catalyst dosage,Al/Ti molar ratio,reaction time and reaction temperature on properties of obtained polymer alpha-olefin（PAO）were investigated.The results show that it is feasible to prepare PAO with Al（Et）2Cl/TiCl4 as catalyst under 50 ℃ for 4 h,yield of oligomer is high and property of product is well.

关 键 词：一氯二乙基铝 四氯化钛 1-癸烯 基础油 

分 类 号：TQ626.3[化学工程—精细化工]