铁络合物催化类Fenton氧化研究进展  

Progress in the research on iron complex catalyzed Fenton-like oxidation

作　　者：郗丽娟[1] 曹天静[1] 李大鹏[1] 杨榕[1] 徐淑芬[1] 廖霞[1] 张瑛洁[1] 

机构地区：[1]东北电力大学化学工程学院,吉林市132012

出　　处：《工业水处理》2011年第7期1-6,共6页Industrial Water Treatment

基　　金：国家自然科学基金项目(50978067);国家科技支撑计划项目(2006BAJ08B02;2006BAJ08B05);"十一五"水专项(2008ZX07421-002;2009ZX07424-005;2009ZX07424-006);东北电力大学博士科研启动基金项目(BSJXM-200904)

摘　　要：综述了铁络合物催化类Fenton氧化的研究进展。铁络合物与铁相比具有更高的催化活性,可提高水中有机物的去除效果。均相类Fenton存在后续金属离子的去除问题,因此铁络合物作为催化剂的多相催化类Fenton氧化具有更好的应用前景。重点介绍了高分子负载铁络合物催化类Fenton氧化降解水中有机物的研究现状及铁络合物催化类Fenton氧化的反应活性物种。The progress in iron complex catalyzed Fenton-like oxidation is reviewed. Compared with iron, the iron complex has a higher catalytic activity to improve the removal rate of organic matter from water. The homogeneous Fenton-like catalyzed by iron complex may bring a problem of removing metallic ions in subsequent process, so the heterogeneous Fenton-like catalyzed by iron complex has a better future. The current research situation of the Fenton-like catalyzed by iron complex loaded on resin is introduced emphatically and the reactive species in the Fenton-like catalyzed by iron complex is discussed.

关 键 词：铁络合物 类FENTON 卟啉 铁酞菁 多相类Fenton 高价态铁 

分 类 号：X703.1[环境科学与工程—环境工程]