多孔炭物理化学结构及其表征  

Physical and Chemical Structures of Porous Carbon and Their Characterizations

作　　者：吴明铂[1] 郑经堂[1] 邱介山[2] 

机构地区：[1]中国石油大学(华东)重质油国家重点实验室,东营257061 [2]大连理工大学化工学院材料化工系炭素材料研究室,大连116012

出　　处：《化学通报》2011年第7期617-627,共11页Chemistry

基　　金：教育部新世纪优秀人才支持计划(NCET-10-0768);教育部科学技术重点项目(109100);国家自然科学基金项目(20876176;20836002;20725619;20976196);中央高校基本科研业务费专项资金(09CX04037A);山东省博士基金项目(2008BS09013)资助

摘　　要：以碳为基本骨架的多孔炭因具有丰富的孔隙结构和表面化学官能团,在吸附分离、催化、电子等领域应用广泛。在阐述多孔炭孔结构(物理结构)和表面化学官能团(化学结构)基础上,重点介绍了透射电镜等可直接观察多孔炭孔结构的表征方法及Dubinin微孔充填理论、平均场密度泛函理论、吸附法、压汞法等表征多孔炭孔结构的主要理论及方法,以及Boehm滴定、X光电子能谱、傅里叶变换红外、拉曼光谱、程序升温脱附等表征多孔炭表面化学结构的常用方法,在此基础上综述了多孔炭物理化学结构方面的最新研究进展。Porous carbons with well-developed multi-scale pore structures and diversifying chemical functional groups have been widely used in many industrial fields including adsorption,separation,catalyst,etc.In this paper,the pore structure and surface chemical structure of porous carbon are discussed.Techniques including SEM and TEM to observe directly pore structures of porous carbon are introduced.Main theories and methods including micropore filling theory,mean-field density functional theory,and adsorption of porous carbon and methods including Boehm titration,X-ray photoelectron spectroscopy,FTIR,Raman spectra,and temperature programmed desorption（TPD） to characterize the surface chemical structure of porous carbon are summarized.Finally,the progresses on the pore and chemical structures of porous carbon are reviewed.

关 键 词：多孔炭 孔结构 表面化学结构 表征 

分 类 号：TQ424.1[化学工程]