氮杂环配体自组装螺旋链状结构配位聚合物的研究进展  

The Research Progress in the Assembly of Helical Coordination Polymers with N-Heterocyclic Ligands

作　　者：钟利娟[1] 鲁晓明[1] 

机构地区：[1]首都师范大学化学系,北京100048

出　　处：《化学通报》2011年第7期668-668,共1页Chemistry

摘　　要：螺旋结构配位聚合物在光学装置、生物模拟化学、非对称催化化学、手性识别、生物结构等多学科领域的应用,引起了人们极大的兴趣。本文综述了氮杂环配体自组装螺旋结构配位聚合物的最新进展,按照咪唑、三唑、吡啶、嘧啶及其衍生物配体分类总结了它们构建螺旋配位聚合物的结构,并简述了通过自发手性识别过程得到纯手性螺旋配位聚合物的影响因素,展望了具有螺旋链状配位聚合物的发展前景以及其开发应用潜能。Helical coordination polymers have attracted great interest in coordination chemistry for their practical implications in multidisciplinary areas,such as optical devices,biomimetic chemistry,asymmetric catalysis chemistry,chiral resolution and structural biology. Herein the construction methodologies of helical coordination polymers using five and/or six-membered N-heterocyclic bridging ligands were briefly reviewed.The significant influences of self-assembling metal cations with chiral bridging ligands on forming chiral helical coordination polymers were discussed. The prospect of helical coordination polymers was also illustrated.

关 键 词：氮杂环 螺旋链 配位聚合物 自组装 

分 类 号：O634[理学—高分子化学]