正丙基缩水甘油醚的合成  

Synthesis and Characterization of 1-propanol Glycidyle Ether

作　　者：王树民[1,2] 周伟良[2] 彭礼婵[3] 段涛[3] 

机构地区：[1]西南科技大学分析测试中心,四川绵阳621010 [2]南京理工大学化工学院,江苏南京210094 [3]西南科技大学极端条件物质特性实验室,四川绵阳621010

出　　处：《广东化工》2011年第7期6-7,共2页Guangdong Chemical Industry

基　　金：四川省教育厅基金(09ZC009);西南科技大学博士基金(07ZX7130)

摘　　要：以正丙醇和环氧氯丙烷为原料,三氟化硼乙醚络合物为催化剂,合成正丙基缩水甘油醚。通过实验研究,系统讨论了原料摩尔比、催化剂用量、反应温度、反应时间和碱用量对合成正丙基缩水甘油醚产率的影响。正丙基缩水甘油醚的产率达到78.1%。通过傅立叶变换红外光谱对其结构进行了表征。1-propanol glycidyl ether was synthesized with l-propanol and epichlorohydrin with trifluorideboron ether complex as catalyst. In the paper, the effect of different conditions, such as molar ratio of reactant, reaction temperature and time, the amount of catalyst and alkali on the yield of 1-propanol glycidyl ether were investigated. The yield of l-propanol glycidyl ether was 78.1%. The product was characterized by FTIR.

关 键 词：正丙醇 环氧氯丙烷 缩水甘油醚 合成 

分 类 号：TQ223.24[化学工程—有机化工]