电子用高纯二氧化钛制备方法研究  

Research on Preparation of High-Purity TiO_2 for Electronic Industry

作　　者：罗志强[1,2] 杜剑桥[1,2] 

机构地区：[1]攀钢集团研究院有限公司,成都611731 [2]钒钛资源综合利用国家重点实验室,四川攀枝花617000

出　　处：《涂料工业》2011年第8期31-33,38,共4页Paint & Coatings Industry

摘　　要：介绍了电子用高纯TiO2的使用领域以及技术特点,简述了电子用高纯TiO2主要制备方法,包括硫酸法、TiCl4直接水解法、氯化法、钛醇盐水解法;详细阐述了各种制备方法的原理、工艺流程、工艺控制、产品质量;对各种制备方法在工艺、设备、成本等方面进行了对比。硫酸法和TiCl4直接水解法因具有工艺简单、产品质量好等优点,在国内已实现了工业化。氯化法和钛醇盐水解法因生产技术难度大、设备材质要求苛刻等方面的原因,仍处于实验室研究阶段。并提出了工业应用的建议以及今后研究的方向。This article has described the application fields and technical characteristics of high - purity TiO2 for electronic industry. The main preparation methods of high - purity TiO2 were reviewed, including sulfate process, TiCl4 direct hydrolysis, chlorinate process, and hydrolysis of titanium alkoxide. The principle, technological process, process control, product quality, and the comparison of corresponding preparation methods in terms of technology, equipment and cost were described. The sulfate process and TiCl4 direct hydrolysis have industrialized already because of their simple processes and high quality products and the chlorination process and hydrolysis of titanium alkoxide are still in lab experiment because of their technical difficulties and strict requirement for equipment material. The industrial application and future research trend of high - purity TiO2 preparation methods were proposed.

关 键 词：高纯TiO2 制备方法 硫酸法 TiCl4水解法 氯化法 钛醇盐水解法 

分 类 号：TQ134.11[化学工程—无机化工]