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机构地区:[1]Department of Materials Science and Engineering,Saveh Branch,Islamic Azad University
出 处:《Science China(Technological Sciences)》2011年第9期2327-2338,共12页中国科学(技术科学英文版)
摘 要:In this work, strength assessments and percentage of water absorption of self compacting concrete containing ground granulated blast furnace slag (GGBFS) and A1203 nanoparticles as binder have been investigated. Portland cement was replaced by different amounts of GGBFS and the properties of concrete specimens were investigated. Although it negatively impacts the physical and mechanical properties of concrete at early ages of curing, GGBFS was found to improve the physical and mechanical properties of concrete up to 45 wt% at later ages. A1203 nanoparticles with the average particle size of 15 nm were added partially to concrete with the optimum content of GGBFS and physical and mechanical properties of the specimens were measured. A1203 nanoparticle as a partial replacement of cement up to 3.0 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca(OH)2 amount at the early ages and hence increase strength and improve the resistance to water permeability of concrete specimens. The increase of the A1203 nanoparticles' content by more than 3.0 wt% would cause the reduction of the strength because of the decreased crystalline Ca(OH)2 content required for C-S-H gel formation. Several empirical relationships have been presented to predict flexural and split tensile strength of the specimens by means of the corresponding compressive strength at a certain age of curing. Accelerated peak appearance in conduction calorimetry tests, more weight loss in thermogravimetric analysis and more rapid appearance of the peaks related to hydrated products in X-ray diffraction results, all indicate that A1203 nanoparticles could improve mechanical and physical properties of the concrete specimens.
关 键 词:CONCRETE ground granulated blast furnace slag (GGBFS) Al203 nanoparticles compressive strength flexural and splittensile strength pore structure thermogravimetric analysis conduction calorimetry
分 类 号:X757[环境科学与工程—环境工程]
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