复合CMA环保型融雪剂的融冰能力研究  

The Research on Ice-melting Capacity of Composite CMA Environment-friendly Deicer

作　　者：许英梅[1] 王丽萍[2] 祁恩云[2] 王明铭[1] 张伟[1] 姜久兴[2] 王冰[1] 

机构地区：[1]大连民族学院生物化工国家民委-教育部重点实验室生命科学学院,辽宁大连116600 [2]哈尔滨理工大学应用科学学院,黑龙江哈尔滨150080

出　　处：《化学世界》2011年第7期404-406,共3页Chemical World

基　　金：辽宁省自然科学基金项目资助(20052199)

摘　　要：采用自制的工业化试验装置和工艺流程,以生物质(秸秆、木屑等)热解废液(木醋液)为原料,制备出以醋酸钙镁盐为主要成分的CMA类环保型融雪剂。研究了复合CMA环保型融雪剂的融冰能力及其不同组分配比对融冰能力的影响规律,结果表明:当液体融雪剂(20%)中醋酸镁和醋酸钙的体积比达到7∶3时融冰能力达到最大值91%,达到了国家标准(GB/T 23851-2009)中的规定值90%。当与一定比例的氯化镁复配后,可提高其融冰能力,液体融雪剂(20%)中氯化镁∶醋酸镁∶醋酸钙=7∶2∶1(体积比)时,融雪剂的融冰能力可达114%,是一种兼具低腐蚀性和高融冰能力的低成本的环保型融雪剂。Using biomass（straw,wood,etc） pyrolytic wastewater as raw material,an environment-friendly deicer consisting mainly of calcium magnesium acetate（CMA） was prepared by industrial self-made device and process.The ice-melting capacity of CMA deicer and the influence of proportion of different components on ice-melting ability were studied.The results showed that the ice-melting capacity reached the maximum（91%）which meets the specified value（90%） of the national standard（GB/T 23851-2009） when the volume ratio of magnesium acetate and calcium acetate in liquid deicer（20%） was7∶3.The ice-melting capacity was improved when a certain proportion of magnesium chloride was added.When the volume ratio（MgCl2∶Mg（CH3COO）2∶Ca（CH3COO）2） was 7∶2∶1,the ice-melting capacity of this deicer reached 114%.The composite CMA deicer is an environmental-friendly deicer which has the advantages of high performance,low cost and corrosion.

关 键 词：木醋液 复合CMA环保型融雪剂 融冰能力 

分 类 号：X783[环境科学与工程—环境工程]