一种液晶共聚酯/粘土纳米复合材料的制备及其相转变温度  

STUDY ON PREPARATION AND PHASE TRANSITION TEMPERATURE OF LIQUID CRYSTAL COPOLYESTER/CLAY NANOCOMPOSITES

作　　者：姜翠红[1] 张广利[1] 张鸿志[1] 漆宗能[2] 

机构地区：[1]北京大学化学与分子工程学院,北京100871 [2]中国科学院化学研究所,北京100080

出　　处：《高分子学报》1999年第6期765-769,共5页Acta Polymerica Sinica

基　　金：中国科学院化学研究所工程塑料国家重点实验室资助

摘　　要：The liquid crystalline copolyester (LCP)/montmorillonite nanocomposites were prepared by polycondensation of terephthalic acid, p \|acetoxy benzoic acid and 1,2\|diacetoxy benzene,in the presence of an organically modified montmorillonite(OMt) with p \|aminobenzoic acid hydrochloride.The cleavage effect of OMt and the liquid\|crystalline behavior of the composites were described.\;The cleavage effect of OMt was examined by X\|ray diffraction (XRD) and transmission electron microscopy (TEM).Room\|temperature XRD spectra were collected from 2θ=2° to 2θ=10°. The eventual disappearance of any distinct X\|ray diffraction peaks for the hybrid containing 2,3,or 5wt% OMt indicated the well dispersion of its original layer structure.The TEM micrograph showed that the silicate layer spacings were greater than 3nm,even some layers dispersed in polymer matrix individually.\;The glass transition temperature T \-g of the LCP/OMt nanocomposites increased slightly as compared with the pure polymer,but the isotropic temperatues T i decreased more significantly as the content of OMt increased.As the clay content increased up to 3%,the decrease of T i reached 25℃.LCP chains separated in certain degree by inorganic phase decreased the ordering ability of mesogenic units.This may be the principal reason for the descent of T i.\;The nematic texture of nanocomposites was observed by POM,and the schlieren texture became indistinct as the clay content increased.Although the schlieren texture in POM for the hybrid with clay content up to 5% still could be observed,the evident location of disinclination point already cant be found.Thus,the mechanism of disinclination in nematic phase for LCP hybrid with OMt is more complicated than that for pure polymer.The liquid crystalline copolyester (LCP)/montmorillonite nanocomposites were prepared by polycondensation of terephthalic acid, p \|acetoxy benzoic acid and 1,2\|diacetoxy benzene,in the presence of an organically modified montmorillonite(OMt) with p \|aminobenzoic acid hydrochloride.The cleavage effect of OMt and the liquid\|crystalline behavior of the composites were described.\;The cleavage effect of OMt was examined by X\|ray diffraction (XRD) and transmission electron microscopy (TEM).Room\|temperature XRD spectra were collected from 2θ=2° to 2θ=10°. The eventual disappearance of any distinct X\|ray diffraction peaks for the hybrid containing 2,3,or 5wt% OMt indicated the well dispersion of its original layer structure.The TEM micrograph showed that the silicate layer spacings were greater than 3nm,even some layers dispersed in polymer matrix individually.\;The glass transition temperature T \-g of the LCP/OMt nanocomposites increased slightly as compared with the pure polymer,but the isotropic temperatues T i decreased more significantly as the content of OMt increased.As the clay content increased up to 3%,the decrease of T i reached 25℃.LCP chains separated in certain degree by inorganic phase decreased the ordering ability of mesogenic units.This may be the principal reason for the descent of T i.\;The nematic texture of nanocomposites was observed by POM,and the schlieren texture became indistinct as the clay content increased.Although the schlieren texture in POM for the hybrid with clay content up to 5% still could be observed,the evident location of disinclination point already cant be found.Thus,the mechanism of disinclination in nematic phase for LCP hybrid with OMt is more complicated than that for pure polymer.

关 键 词：液晶聚酯 纳米复合材料 蒙脱土 插层聚合 

分 类 号：TB332[一般工业技术—材料科学与工程]