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作 者:刘云明[1] 尹昌耕[1] 孙长龙[1] 陈建刚[1] 孙旭东[1]
机构地区:[1]中国核动力研究设计院反应堆燃料及材料重点实验室,成都610041
出 处:《核动力工程》2011年第4期19-23,共5页Nuclear Power Engineering
摘 要:采用扩散偶方法研究了U-Mo合金与Al扩散反应特征。扩散偶以热压方式实现持续贴合。实验在真空热压炉中完成,热压温度550~570℃,时间5~21 h。结果表明:U-Mo/Al扩散层界面形貌和成分与扩散层厚度有关;在扩散层界面处U、Mo和Al的含量突变;U-Mo侧扩散层产物主要为(U,Mo)Al3,Al侧产物为(U,Mo)Al4和UMo2Al20。U-Mo/Al扩散反应是Al越过U-Mo/Al原始界面向U-Mo侧扩散并发生固体反应和扩散层向Al层生长的过程。In this paper,the interaction behavior of U-Mo/Al was studied with the diffusion-couple method,and the couple was continuously jointed by hot-pressing with special device.Annealing experiments were accomplished in a vacuum hot-pressing furnace,and at 550~570℃ for 5~21hours.The results show that the morphology and composition of interaction Layer depend on the interaction layer thickness.The con-tent of U(Mo) and Al is mutational at the interface of U-Mo/interaction layer/Al.The layer close to U-Mo side is mainly composed of product(U,Mo)Al 3,while the Al side is composed of(U,Mo)Al 4 and UMo 2 Al 20.Diffusion process of U-Mo/Al is Al immigrating over the Al/U-Mo original interface into U-Mo side and re-acting with U-Mo,subsequently the interaction layer is growing into Al.
分 类 号:TL341[核科学技术—核技术及应用]
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