Double perovskite oxides Sr_2Mg_(1-x)Fe_xMoO(6-δ) for catalytic oxidation of methane  

作　　者：Chen Li Wendong W ang Congying Xu Yuanxu Liu BO He Chusheng Chen 

机构地区：[1]CASKeyLaboratoryofMaterialsforEnergyConversion,UniversityofScienceandTechnologyofChina,Hefei230026,Anhui,China [2]DepartmentofChemicalPhysics,UniversityofScienceandTechnologyofChina,Hefei230026,Anhui,China [3]NationalSynchrotronRadiationLaboratory,UniversityofScienceandTechnoiogvofChina,Hefei230029,Anhui,China： [4]Department ofChemistry and Chemical Engineering,Huainan Normal University,Huainan 232001,Anhui,China

出　　处：《Journal of Natural Gas Chemistry》2011年第4期345-349,共5页天然气化学杂志（英文版）

基　　金：the financial supports from the National Natural Science Foundation of China(No.20703042);National Basic Research Program of China(No.2010CB923300);USTC-NSRL Association Funding(No.KY2060030009);the Fundamental Research Funds for the Central Universities

摘　　要：The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible（Fe2＋,Mo6＋） and （Fe3＋,Mo5＋）valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies.The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible（Fe2＋,Mo6＋） and （Fe3＋,Mo5＋）valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies.

关 键 词：catalytic combustion METHANE double perovskites Sr2Mg1-xF exMoO6-δ SOFC anode materials 

分 类 号：O614.33[理学—无机化学] TE665.3[理学—化学]