甲烷部分氧化制合成气催化剂的研究进展  

Progress on Catalyst of Partial Oxidation of Methane to Syngas

作　　者：李航[1] 殷洁炜[2] 王幸宜[1] 尹屹梅[2] 马紫峰[2] 

机构地区：[1]华东理工大学工业催化研究所,上海200237 [2]上海交通大学化学工程系,上海200240

出　　处：《广州化工》2011年第15期4-6,36,共4页GuangZhou Chemical Industry

基　　金：国家自然科学基金项目(20973111);上海市自然科学基金项目(09ZR1413900);上海市国际合作项目(10520708900)

摘　　要：甲烷部分氧化(POM)反应制合成气是化学利用甲烷的有效途径之一。研究表明,甲烷部分氧化反应的工艺有能耗低和反应速率较快等优点,而且所得的H2和CO的比例适于合成甲醇等工业化学品。在该工艺过程中,所需反应容器体积小,反应效率高,可大幅度降低制备合成气的成本。开发POM反应的高效催化剂是进一步提高反应效率、实现工业化的关键途径,因此,是当前国际催化领域研究的热门课题之一。本文主要介绍了传统的金属负载型催化剂和金属氧化物催化剂用于POM反应的研究进展。Partial oxidation of methane（POM） to syngas was one of effective pathes to chemical use of methane.The advantages of POM＇s technology were lower energy consumption,faster reaction rate and suitable ratio of H2/CO products for synthesis of industrial chemicals,for example,methanol.Moreover,the needed reactor was smaller and the reaction efficiency was relatively higher for POM technology,which can significantly reduce the cost of syngas production.Nowadays,exploiting catalysts with higher activity for POM reaction was a key approach to higher efficiency and industrialization of POM.Therefore,it was currently one of the hottest topics in global catalytic field.The research progress of POM to syngas was surmmerized briefly,focusing on conventional supported-metal catalysts and metallic oxide catalysts on POM.

关 键 词：甲烷部分氧化 催化剂 合成气 

分 类 号：TQ325.14[化学工程—合成树脂塑料工业]