含活性官能团光响应单体的合成及表征  

Synthesis and Characterization of an Active Photoresponsive Functional Monomer

作　　者：常文斌[1] 张广播[1] 唐倩[1] 龚成斌[1] 马荣[1] 李向亮[1] 

机构地区：[1]西南大学化学化工学院,重庆400715

出　　处：《西南大学学报（自然科学版）》2011年第5期59-62,共4页Journal of Southwest University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(20872121);重庆市自然科学基金资助项目(CSTC;2009BB4001);西南大学博士基金资助项目(SWU2008075);西南大学博士后基金资助项目

摘　　要：以对氨基苯甲酸为原料经酯化、重氮-偶合、烷基化取代和硫代反应合成了含巯基羧基的光响应性功能单体,获得了较好的收率.用1H-NMR证实了该功能单体的结构,并研究了其光响应性能.With aminobenzoic acid as the raw material,a photo-responsive functional monomer,containing carboxyl and mercaptan group azobenzene,was prepared by esterification,diazotization-coupling reaction,alkyl substitution and thiosulfate reaction,and the yield was good.The structure of the functional monomer was confirmed by 1H-NMR and its photoresponsive properties were studied.

关 键 词：巯基羧基偶氮苯 光响应性 合成 

分 类 号：TQ594[化学工程—精细化工]