Meso-取代卟啉及其金属配合物的合成进展  

The Advances in Synthesis of Meso-Substitute Porphyrins and Metalloporphyrins

作　　者：杨晓杰[1] 沈阳[1] 张莹[1] 谭伶玉[1] 张晓娟[1] 

机构地区：[1]沈阳工业大学石油化工学院,辽宁辽阳111003

出　　处：《广州化工》2011年第16期13-16,共4页GuangZhou Chemical Industry

摘　　要：为了筛选仿生催化氧化环己烷的催化剂,通过查阅相关文献,重点概述了Meso-取代卟啉及其金属配合物的合成方法。合成卟啉的方法有Rothemund法、Adler法及其改进法、Lindsey法等,合成金属卟啉的方法有"一步法"和:"两步法",目前,"两步法"被普遍使用。In order to select a catalyst for biomimetic catalytic oxidation of cyclohexane,base on referring a large number of related literature,the method of synthesizing Meso-substitute porphyrin and its metal complexes were summarized emphatically.The method were Rothemund,Adler and its improvement act,Lindsey,and so on.The methods of synthesizing metallo-porphyrins were called ＂one step＂ and ＂two-step-method＂,nowadays,＂two-step method＂ was used commonly.

关 键 词：卟啉 金属卟啉 合成 

分 类 号：O641.4[理学—物理化学]