介孔分子筛负载金属卟啉的研究进展  

Review on Metalloporphrins Immobilized on Mesoporous Molecular Sieves

作　　者：王乔乔[1] 白金泉[1] 董阳阳[1] 

机构地区：[1]北京工业大学环境与能源工程学院化学化工系,北京100124

出　　处：《广东化工》2011年第8期57-59,共3页Guangdong Chemical Industry

基　　金：北京市学术创新团队计划(项目号PHR201107104)

摘　　要：文章介绍了介孔分子筛负载金属卟啉的合成工艺方法,包括浸渍法、离子交换法、水热合成法、接枝法和"瓶中造船"法。其中,主要介绍了常用的离子交换法和接枝法。开发新的负载方法增强孔道表面嫁接的卟啉衍生物的稳定性,具有重要的意义。Research progress in methods for preparation of imobilized metalloporphyrins catalysts have been reviewed in the paper. Five methods have been described, containing impregnation, ion-exchange, hydrothermal synthesis, grafting and ship in bottle method. Ion-exchange and grafting method have been described in detail. It was of importance for developing new method to enhance the stability of metalloporphytins on the mesoporous sieves.

关 键 词：金属卟啉:介孔分子筛 负载 

分 类 号：TQ426.6[化学工程]