中温固体氧化物燃料电池电解质YSZ薄膜的低温制备和性能表征  

Low Temperature Fabrication and Properties of YSZ Membrane for IT-SOFC

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作  者:王娇燕[1] 王玉灵[1] 金惠梅[1] 马兵兵[1] 周燕燕[1] 王雁鹏[1] 闫瑞强[1] 

机构地区:[1]台州学院医药化工学院,临海317000

出  处:《科学技术与工程》2011年第24期5805-5808,共4页Science Technology and Engineering

摘  要:考察了少量氧化钴对YSZ粉体烧结性能的影响。结果发现,YSZ粉体中添加0.5 mol%氧化钴后,YSZ电解质1 200℃即可烧结致密,比未掺杂时降低了200℃。利用空气喷涂法制备的添加氧化钴的YSZ薄膜在1 280℃制作的单电池,在800℃时OCV和最大输出功率分别为1.02 V和353 mW/cm2,结果表明薄膜已经完全致密。The sintering and conductivity properties of YSZ powder doped with a small quantity of cobalt oxide were investigated.Experiment results indicate that after being doped with small quantities of impurity,the sintering ability of the powder increases linearly a lot and densification is reached under 1 200 ℃,which is about 200 ℃ less than cases without doping.A single cell with YSZ electrolyte membrane doped with 0.5 mol% cobalt oxide fabricated by particle suspension spraying was sintered at 1 280 ℃ temperature.The open circuit voltage(OCV) and peak power density of the single cell are 1.02 V and 353 mW/cm2,respectively,which shows the YSZ membrane is quite dense.

关 键 词:燃料电池 电解质 YSZ 薄膜 低温 

分 类 号:TM911.48[电气工程—电力电子与电力传动]

 

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