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机构地区:[1]Key Laboratory of Bioinorganic and Synthetic Chemistry,Ministry of Education,State Key Laboratory of Optoelectronic Materials and Technologies,School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,China [2]Key Laboratory of Organo-Pharmaceutical Chemistry of Jiangxi Province,College of Chemistry&Life Science,Gannan Normal University,Ganzhou 341000,China
出 处:《Science China Chemistry》2011年第9期1395-1406,共12页中国科学(化学英文版)
摘 要:During the last two decades,porous coordination polymers(PCPs),usually called as metal-organic frameworks(MOFs),have been developed rapidly due to their versatile structural diversities and potential physical and chemical functions.This article provides a short review of recent advances in the design and constructions of porous coordination polymers based on three planar rigid ligands,including imidazole-4,5-dicarboxlate(H3IDC),1H-tetrazole(HTz),as well as 1H-tetrazole-5-carboxylate(H2Tzc).Their preparations,crystal structures,and desirable properties have been reviewed.During the last two decades,porous coordination polymers(PCPs),usually called as metal-organic frameworks(MOFs),have been developed rapidly due to their versatile structural diversities and potential physical and chemical functions.This article provides a short review of recent advances in the design and constructions of porous coordination polymers based on three planar rigid ligands,including imidazole-4,5-dicarboxlate(H3IDC),1H-tetrazole(HTz),as well as 1H-tetrazole-5-carboxylate(H2Tzc).Their preparations,crystal structures,and desirable properties have been reviewed.
关 键 词:porous coordination polymers metal-organic frameworks planar rigid ligands imidazole-4 5-dicarboxlate 1H-tetrazole 1H-tetrazole-5-carboxylate
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