手性咪唑酯类离子液体的合成及其物理性能  

Synthesis of Chiral Imidazole Ester Ionic Liquids and Their Physical Properties

作　　者：闻立新[1] 向自伟[1] 宗乾收[2] 缪程平[2] 吴建一[1,2] 

机构地区：[1]常州大学石油化工学院,江苏常州213164 [2]嘉兴学院生物与化工学院,浙江嘉兴314001

出　　处：《合成化学》2011年第5期600-604,共5页Chinese Journal of Synthetic Chemistry

基　　金：浙江省自然基金资助项目(Y406470)

摘　　要：以咪唑,溴代烷烃及(-)-薄荷醇为原料合成了12个手性咪唑酯类离子液体,其结构经NMR和IR表征。物理性能研究结果表明,该类离子液体具有较好的热稳定性,且比旋光度存在一定的改变规律。Twelve novel chiral imidazole ester ionic liquids were designed and synthesized from imidazole, brominated alkanes and （ -）-menthol. The structures were characterized by NMR and IR. The results showed that the ionic liquids exhibited good thermal stability and the specific rotation showed regular changes.

关 键 词：咪唑 (-)-薄荷醇 手性离子液体 合成 物理性能 

分 类 号：O626.3[理学—有机化学]