1,3,5-三(4-二苯胺基苯乙炔基)-2,4,6-三(4-腈基苯乙炔基)苯的合成及表征  

Synthesis of 1,3,5-tris[4-(diphenylamino)phenylethynyl]-2,4,6-tris(4-cyanophen ylethynyl)Benzene and Characterization

作　　者：于波[1] 朴明俊 于海岩 张龙[2] 

机构地区：[1]长春中医药大学药学院,吉林长春130117 [2]长春工业大学化学工程学院,吉林长春130012 [3]中石油吉林石化分公司电石厂,吉林吉林132021

出　　处：《广东化工》2011年第9期28-29,共2页Guangdong Chemical Industry

摘　　要：利用微波反应合成了一种新型二阶非线性光学化合物1,3,5-三(4-二苯胺基苯乙炔基)-2,4,6-三(4-腈基苯乙炔基)苯,通过红外、核磁共振、元素分析等手段对产物结构进行了表征。紫外可见光的吸收光谱的研究表明,该产物有希望成为1064 nm激光的倍频材料。A new second-order nonlinear optical compound,1,3,5-tris [4-（diphenylamino）phenyl-ethynyl]-2,4,6-tris（4-cyanophen ylethynyl）benzene,which using phenylethynyl as conjugation bridge between electron-donor and acceptor,was synthesized by microwave reaction.Characterization was carried by FTIR,NMR,elemental analysis,and UV-VIS absorption was investigated.

关 键 词：二阶非线性光学材料 苯乙炔 紫外可见光吸收 

分 类 号：TQ[化学工程]