固态质子导体型燃料电池反应器  

Proton-Conducting Membrane Fuel Cell Reactors

作　　者：方亮[1] 王万丽[1] 尹屹梅[1] 马紫峰[1] 

机构地区：[1]上海交通大学化学工程系电化学与能源技术研究所,上海200240

出　　处：《化学反应工程与工艺》2011年第3期269-279,共11页Chemical Reaction Engineering and Technology

基　　金：国家自然科学基金(20973111);上海市自然科学基金(09ZR1413900);上海市博士后科研资助(09R21414200);中国博士后科学基金(20090450696)

摘　　要：将固态质子导体型燃料电池作为新型反应器用于合成化学品,产物选择性高,能耗低,可以实现电能与化学品共生。通过对反应器操作参数的调变,可以获得预期的化学产品及相应的电化学特性。本工作综述了固态质子导体型燃料电池反应器在简单无机物加氢、具有不饱和键脂肪族和芳香族化合物加氢、醇脱氢以及烷烃脱氢等反应中的应用。随着对该反应过程认识的不断深入,可望开辟一条崭新的化学品合成途径。The proton-conducting membrane fuel cell reactors can be used in the production of chemicals with high selectivity, low energy consumption, and cogeneration of energy. The prospective chemicals and corresponding electricity characteristics can be obtained via adjusting the process parameters. The applications of proton-conducting membrane fuel cell reactors in some typical reactions were reviewed, such as the production of hydrogen peroxide, hydrogenation of carbon dioxide, unsaturated hydrocarbon, and oil, and the dehydrogenation of alcohol and alkane, etc. It is expected that further studies on this type of reactors are still needed to open up a new way for the practical chemical production.

关 键 词：固态质子导体 燃料电池反应器 加氢反应 脱氢反应 电能与化学品共生 

分 类 号：TM911.48[电气工程—电力电子与电力传动] TQ031.4[化学工程]