硅杂环戊二烯的合成及应用研究进展  

Progress in the Synthesis and Applications of Silole Compounds

作　　者：马庆宇[1] 关瑞芳[1] 李国忠[1] 冯圣玉[2] 

机构地区：[1]济南大学材料科学与工程学院,济南250022 [2]山东大学化学与化工学院,济南250100

出　　处：《有机化学》2011年第9期1395-1405,共11页Chinese Journal of Organic Chemistry

基　　金：山东省科技攻关计划(No.2008GG30003009);山东省博士基金(No.BS2009CL0153)资助项目

摘　　要：硅杂环戊二烯是一种含硅的五元环,是环戊二烯的类似物,由于其具有特殊的电子结构,在许多方面有广泛的应用.综述了硅杂环戊二烯化合物的合成方法,作为光电材料、化学传感器及生物传感器等方面的应用研究进展.最后,对硅杂环戊二烯的研究方向提出了展望.Siloles are a group of silicon-containing five-membered cyclic dienes.Due to their unique electronic structures,they have been attracted much attention and potentially applied in many fields.In this review,we summarized recent progress in the synthesis of silole compounds and their applications as electroluminescent devices（EL）,chemsensors,biosensors etc.Opposite to common phenomenon of aggregation-caused quenching（ACQ） of light emission in many luminophoric molecules,silole compounds exhibit aggregation-induced emission（AIE）.Enlightened by this abnormal phenomenon,the applications of silole compounds are extremely extended,including traditional EL materials,chem-,bio-sensors and many fields in progress.At last,the future research of this research field is also prospected.

关 键 词：硅杂环戊二烯 聚集诱导发光 光电材料 化学传感器 生物传感器 

分 类 号：O627.41[理学—有机化学]