四溴双酚A在玻碳电极上的电化学行为  

Electrochemical Behavior of Tetrabromobisphenol Aon Glassy Carbon Electrode

作　　者：占春荣[1] 黄颖[1] 肖佳[1] 郑少华[1] 许丹凤[1] 林云燕[1] 毛艺[1] 

机构地区：[1]福建师范大学化学与材料学院,福建福州350108

出　　处：《福建师范大学学报（自然科学版）》2011年第5期62-66,共5页Journal of Fujian Normal University：Natural Science Edition

基　　金：福建省属高校科研专项(JK20100008);福建师范大学本科生课外科技计划(BKL2010-026);福建省大学生创新性实验计划项目(Fjnu2010-006)

摘　　要：采用循环伏安法研究四溴双酚A(TBBPA)在玻碳电极上的电化学行为,建立了TBBPA的差分脉冲伏安分析法.结果表明,在pH6.0的磷酸盐缓冲溶液中,0.3～1.0V电位区间内,TBBPA在玻碳电极表面发生的电极反应是受扩散控制的不可逆等电子、质子转移过程.以差分脉冲伏安法测得其氧化峰电流与其浓度在0.1～5.0μmol.L-1范围内呈良好的线性关系,检测限为39.2nmol.L-1(S/N=3),重复测定的相对标准偏差(RSD)为3.0%(n=7),回收率为86.7%～100.4%.The electrochemical behavior of tetrabromobisphenol A was studied on a glassy carbon electrode, and differential pulse voltammetric method for the determination of tetrabromobisphenol A was established. The results showed that a diffusion-controlled pro- cess was occurred on the electrode and the electron transfer was accompanied by an equal number of proton in electrode reaction. It shows good linear relationship between peak current and the concentration of tetrabromobisphenol A in the range of 0.1 to 5.0μmol ·L-1 by differential pulse voltammetry. The detection limit （S/N = 3） for this method is 39.2 nmol · L-1. The relative standard deviation is 3.0% （n =7） , and the recovery is between 86.7% to 100. 4%.

关 键 词：四溴双酚A 电化学行为 差分脉冲伏安法 

分 类 号：O657.1[理学—分析化学]