一种纤维用新型聚乙二醇固-固相变储能材料  

A Novel Polyethylene Glycol Solid-Solid Phase Change Energy Storage Material for Fiber

作　　者：段玉情[1] 西鹏[1,2] 刘然[1] 何春娥[1] 

机构地区：[1]天津市纤维改性与功能性纤维重点实验室天津工业大学,天津300387 [2]高分子物理与化学国家重点实验室中国科学院化学研究所,北京100080

出　　处：《合成纤维》2011年第9期13-18,共6页Synthetic Fiber in China

基　　金：天津市应用基础及前沿技术研究计划项目(10JCYBJC03100)

摘　　要：根据固-固相变材料的性质与结构特点,通过分子设计合成出了一种新型的芳香族四羟基化合物——4,4'-二苯基甲烷二异氰酸甘油酯(MTE),同时以4,4'-二苯基甲烷二异氰酸酯(MDI)-MTE为硬段,以聚乙二醇为相变单元和软段,通过原位聚合法制备出了一种聚乙二醇固-固相变储能材料(P-PCM)。利用红外光谱、核磁共振光谱、差示扫描量热法、动态热机械分析法研究了P-PCM的结构、相变行为及热稳定性,表明了P-PCM是一种新型的性能优异的相变材料。由于材料的刚性、可熔融和可溶解性,适合于纤维与织物的加工使用。In this paper, a novel aromatic tetrahydroxy compound glycerin diphenyl-methane-diisocyanate （MTE） was synthesized through molecular design, basing on the properties and structure characteristics of solid-solid phase change materials. Moreover, one kind of polyethylene glycol solid-solid phase change heat storage material with MDI-MTE-based hard segmentsa and PEG-based phase change unit and soft segments were prepared by in-situ polymerization. KFIR, ^1H NMR, DSC and DMA were used to study the structure characterization, phase change behavior and thermal stability. The results indicated that a novel phase change materials of superior performance was synthesized. At the same time, due to the rigidity and solubility of the materials, all of these can be satisfied for fiber and fabric.

关 键 词：聚乙二醇 芳香族四羟基化合物 固-固相变材料 

分 类 号：TB34[一般工业技术—材料科学与工程]