Multilayered Ti-Al intermetallic sheets fabricated by cold rolling and annealing of titanium and aluminum foils  

冷轧热处理钛-铝箔制备微叠层Ti-Al系金属间化合物板材(英文)

作　　者：孙彦波[1] 赵业青[1] 张迪[1] 刘翠云[1] 刁浩岩[1] 马朝利[1] 

机构地区：[1]北京航空航天大学材料科学与工程学院空天先进材料与服役教育部重点实验室,北京100191

出　　处：《Transactions of Nonferrous Metals Society of China》2011年第8期1722-1727,共6页中国有色金属学报（英文版）

基　　金：Project (2010DFA51650) supported by the Ministry of Science and Technology of China

摘　　要：Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering conditions were evaluated by various techniques.The results reveal that when the sintering temperature is above the melting point of aluminum,the self-propagating high-temperature synthesis reaction occurs between Ti and Al,and forms various phases of Ti-based solid solutions including α-Ti Ti3Al,TiAl,TiAl2 and α-Ti including TiAl3,etc.When the sintering time increased,Ti-based solid solution,TiAl2 and TiAl3 disappeared gradually,and the sheet containing Ti3Al and TiAl phases in a multilayered structure formed finally.A lot of voids were also observed in the sintered structures,which were caused by the melting Al,Kirkendall effect and the difference of molar volumes between reactants and products.The voids were eliminated and a dense sample was obtained by the following hot press.通过钛箔、铝箔叠加烧结制备出微叠层Ti-Al系金属间化合物合金板材。对不同烧结条件下获得的板材组织和相组成进行分析。结果表明,当烧结温度到达到Al的熔点以上时,高温自蔓延反应(SHS)在Ti箔和Al箔之间发生,生成α-Ti、Ti3Al、TiAl、TiAl2和TiAl3等相;随着烧结时间的延长,α-Ti、TiAl2和TiAl3逐渐消失,最终获得包含Ti3Al和TiAl的叠层结构板材。由于铝的熔化,柯肯达尔效应和反应前、后摩尔体积的变化在烧结过程中产生大量的孔洞,随后的热压处理将孔洞消除并获得致密的合金板材。

关 键 词：multilayered composites Ti-Al based intermetallics self-propagating high-temperature synthesis voids cold rolling ANNEALING 

分 类 号：TG335.12[金属学及工艺—金属压力加工]