生物质化学组分及其液化残渣的热重行为  

TG study on major biomass components and its liquefied residues from pyrolysis

作　　者：张海荣[1,2] 庞浩[1] 石锦志[1] 廖兵[1] 

机构地区：[1]中国科学院广州化学研究所纤维素化学重点实验室,广东广州510650 [2]中国科学院研究生院,北京100039

出　　处：《化工进展》2011年第10期2194-2199,共6页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金委员会NSFC-广东联合基金(U0834005);广东省国际合作项目(2008B050100016);广东省自然科学基金研究团队项目(E06200692)

摘　　要：分别对木粉主要组分(纤维素、半纤维素和木质素)及其在相同液化条件下的液化残渣的热重行为进行了研究。热重实验结果表明,木粉主要组分的热稳定性为:木质素>纤维素>半纤维素。木粉的热解过程可以认为是这3种主要组分热解行为的综合:木质素的热解比较缓慢,热解温度区间最宽,主要失重温度为250～630℃;而纤维素和半纤维素的主要热解温度分别为332～383℃和236～333℃。在液化反应过程中,木粉主要组分发生降解从易到难的顺序为:木质素>半纤维素>纤维素。在木粉的液化过程中,快速液化阶段主要与半纤维素和木质素有关,而液化残渣率的高低主要与纤维素液化程度有关。The pyrolysis behaviors of wood and its three chemical components（cellulose,hemicellulose and lignin）were investigated in a thermo-gravimetric analyzer（TGA）.Meanwhile,the thermo-gravimetric behavior of liquefied residues under same liquefaction conditions were also studied.Regarding thermal stability,TGA results showed that lignin was the most difficult one to be pyrolyzed,hemicellulose was the easiest one,and cellulose was in the middle.The thermal degradation of wood was considered as the sum of the thermal degradations of each individual chemical component.It was achieved in a step-wise manner,i.e.hemicellulose breaken down first at 236～333 ℃,cellulose next at 332～383 ℃ and lignin at 250～630 ℃.Lignin was the most susceptible wood component to the liquefaction reaction among the three main wood components,then hemicellulose,and cellulose at last.In the liquefaction process,the rapid liquefaction stage was mainly attributed to lignin and hemicellulose,which were easily and firstly liquefied,while the second stage,characterized by the slow decrease of residues,mainly depended upon the progress of cellulose liquefaction.

关 键 词：生物质 化学组分 液化残渣 热重行为 

分 类 号：TQ351[化学工程]