Dicyclopentyl azodicarboxylate(DCpAD):A new alternative azo-reagent for the Mitsunobu reaction  

作　　者：Jian Hai Yang Li Yan Dai Xiao Zhong Wang Ying Qi Chen 

机构地区：[1]Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

出　　处：《Chinese Chemical Letters》2011年第9期1047-1050,共4页中国化学快报（英文版）

摘　　要：Dicyclopentyl azodicarboxylate is introduced as a new azo-reagent which can be conveniently prepared in two steps and be used in the Mitsunobu reaction. Though there are no distinct difference of reactivity between DCpAD and DEAD, the former is a more preferable azo-reagent for its stability.Dicyclopentyl azodicarboxylate is introduced as a new azo-reagent which can be conveniently prepared in two steps and be used in the Mitsunobu reaction. Though there are no distinct difference of reactivity between DCpAD and DEAD, the former is a more preferable azo-reagent for its stability.

关 键 词：Dicyclopentyl azodicarboxylatc Mitsunobu reaction Azo-reagent 

分 类 号：O621.256.7[理学—有机化学] O614.62[理学—化学]