Efficient catalyst-free chemical fixation of carbon dioxide into 2-oxazolidinones under supercritical condition  

作　　者：Jing Xiu Xu Jin Wu Zhao Zhen Bin Jia 

机构地区：[1]School of Pharmacy, Guangdong Medical College, Dongguan 523808, China

出　　处：《Chinese Chemical Letters》2011年第9期1063-1066,共4页中国化学快报（英文版）

基　　金：supported financially by Youth Foundation of Guangdong Medical College(No.XQ1029);Science and Technology Planning Project of Zhanjiang city(No.2009c3103024)

摘　　要：4-Methylene-1,3-oxazolidin-2-ones can be synthesized from propargylic alcohols, primary amines and carbon dioxide under supercritical condition in the absence of any additional catalyst and solvent. Various propargylic alcohols and primary amines were examined.4-Methylene-1,3-oxazolidin-2-ones can be synthesized from propargylic alcohols, primary amines and carbon dioxide under supercritical condition in the absence of any additional catalyst and solvent. Various propargylic alcohols and primary amines were examined.

关 键 词：CATALYST-FREE Carbon dioxide SUPERCRITICAL 2-Oxazolidinone 

分 类 号：TQ426[化学工程] TQ325.14