生物油-甲醇催化转化制氢  

Study on hydrogen production by catalytic reforming of bio-oii-methanol mixture

作　　者：韩红睿[1] 张瑞芹[1] 徐兴敏[1] 张长森[1] 刘永刚[1] 

机构地区：[1]郑州大学环境科学研究院,河南郑州450001

出　　处：《工业催化》2011年第9期48-51,共4页Industrial Catalysis

基　　金：河南省省院技术合作项目(SYHZ2009101)

摘　　要：以生物油-甲醇为原料,在微型固定反应装置上考察实验室合成镍基催化剂重整制氢的催化效率。对反应前后的催化剂进行XRD、BET和SEM表征分析,并对冷凝液做GC-MS分析。研究发现,实验室自制的NiCeMg/olivine催化剂具有较好的催化活性和一定的抗积炭性能。在选择的最佳反应条件下,氢气产率和碳转化率分别为38.52%和68.29%。Using bio-oil-methanol as the raw material, the nickel-based reforming catalyst for hydrogen production prepared in the laboratory was investigated in the fixed micro-reactor. The catalysts before and after reaction were characterized by XRD, BET and SEM. The eondensates collected after gasification were analyzed by GC-MS. The results showed that NiCeMg/olivine catalyst exhibited good catalytic activity and good properties of resistance to carbon deposition. The hydrogen yield of 38.52% and carbon conversion of 68.29% were attained under the the optimum reaction condition.

关 键 词：催化化学 氢气 生物质 甲醇 催化重整 镍基催化剂 

分 类 号：TK6[动力工程及工程热物理—生物能] O643.36[理学—物理化学]