富勒烯衍生物的制备及其表征  

Preparation and Characterization of Fullerene Derivative

作　　者：李保民[1] 赵玉翠[2] 武士威[3] 刘贤豪[1] 韩爱鸿[2] 

机构地区：[1]中国乐凯胶片集团公司,保定071054 [2]沈阳师范大学化学与生命科学学院,沈阳110034 [3]沈阳师范大学实验中心,沈阳110034

出　　处：《信息记录材料》2011年第5期8-10,28,共4页Information Recording Materials

摘　　要：最近太阳能利用技术的快速发展,推动了新材料的研发,特别是在有机聚合物活性材料领域,制备出各种电子供体和受体材料。本研究开发了一条简单的路线,可合成出系列的有机受体材料(富勒烯衍生物),通过利用活性的丙二酸亚异丙酯为起始原料,与对甲氧基苯酚进行酯化反应,高收率的制备了丙二酸对甲氧基苯酚单酯中间体;进一步与含羟基化合物反应(以叔丁醇为例),生成不对称的丙二酸双酯,最后与富勒烯C60进行Bingel反应制备富勒烯衍生物,其电化学性质被表征。Recently rapid developments of solar energy technology promote the research on the new materials, especially, on the synthesis of various donors and acceptors in the fields of organic polymer active materials. An easy route to prepare a series of organic acceptor （fullerene derivative） was found. The malonic acid mono phenol ester was synthesized by Meldrum＇s acid and p-methoxyphenol under a solvent-free condition with high yield, then reacted with compounds containing hydroxyl group （for example,, t-butanol）, asymmetric malonic acid di-ester was prepared, finally a fullerene derivative was synthesized by Bingel reaction, and its electrochemical property was characterized by cyclic-voltammetry （CV）.

关 键 词：丙二酸亚异丙酯 对甲氧基苯酚 富勒烯 光电材料 

分 类 号：TQ31[化学工程—高聚物工业]