侧基官能性乙烯基醚阳离子活性聚合与乙烯基醚阳离子光固化体系  

Advances in Cationic Polymerization of Vinyl Ether with Functional Pendant Group Research

作　　者：庞玉莲[1] 邹应全[1] 

机构地区：[1]北京师范大学化学学院,北京100875

出　　处：《信息记录材料》2011年第5期52-55,共4页Information Recording Materials

基　　金：北京市自然科学基金;编号2112020

摘　　要：本文着重介绍阳离子聚合单体的结构、溶剂及引发体系对活性阳离子聚合技术的影响以及近几年来采用活性阳离子聚合技术制备侧基官能性乙烯基醚聚合物的方法,尤其是应用较广泛的羟基、羧基、氨基等侧基官能化聚合物的合成。研究乙烯基醚阳离子活性聚合,将对乙烯基醚阳离子光固化体系的应用研究具有重要的指导意义。The influence factors such as the structure of cationic monomer, solvent used in reaction and initiating system on the active cationic polymerization were introduced. The mothods in preparation of vinyl ether polymer with functional side groups by cationic polymerization, especially the vinyl ether with a hydroxyl, a carhoxyl or an amino group were sumarrized. Studying the acitve cationic polymerization of vinyl ethers has important guiding significance for the application of cationic light curing system of vinyl ether.

关 键 词：活性阳离子聚合 电子效应 位阻效应 引发体系 侧基官能性乙烯基醚 

分 类 号：TQ31[化学工程—高聚物工业]