金属卟啉催化氧化环己烷反应的研究进展  

Research Progress in Catalytic Oxidation of Cyclohexane by Metalloporphyrins

作　　者：沈阳[1] 杨晓杰[1] 孙巍 张莹[1] 谭伶玉[1] 唐丽华[1] 

机构地区：[1]沈阳工业大学石油化工学院,辽宁辽阳111003 [2]辽阳石油化纤公司金兴化工厂,辽宁辽阳111003

出　　处：《当代化工》2011年第9期936-939,共4页Contemporary Chemical Industry

基　　金：辽宁省教育厅A类项目(05L289)

摘　　要：为了筛选仿生催化氧化环己烷反应的优异催化剂。重点归纳总结了用做仿生催化空气氧化环己烷反应的金属卟啉化合物的类型和种类。其中,研究最为活跃的是中位取代(meso-)四苯基卟啉及其衍生物的金属配合物,络合的金属种类主要是过渡金属Fe、Mn、Co。金属卟啉仿酶催化剂品种中,主要有单金属卟啉、双核金属卟啉和固载金属卟啉等3种类型,其中研究较为成熟的是单金属卟啉催化剂,且苯环上取代吸电子基团的金属卟啉仿酶催化剂的催化活性较高。In order to select an excellent catalyst for biomimetic catalytic oxidation of cyclohexane,types and varieties of metalloporphyrin compounds used in catalytic oxidation of cyclohexane were summarized.Among these metalloporphyrin catalysts,research on the meso-tetraphenylporphyrin and metal complexes of its derivatives was most active.The main metal types of complexation were transition metal Fe,Mn,Co.The single,dual-core and immobilized metalporphyrins were the main types in the species of metalloporphyrins.Study on the single metalporphyrin catalysts was more mature.

关 键 词：金属卟啉 仿生催化剂 催化氧化 环己烷 

分 类 号：O643[理学—物理化学]