Synthesis of Oligohydroxynapthylenes and Their Use in Making of Heat-Stable and Electro-Conducting Rubbers  

作　　者：Bakhtiar Ajdar ogli Mamedov Rita Shahnazarli R. S. Rzaev Nelli Ishenko Khayyam Guvvat ogli Nazaraliev Mubariz Meyti ogli Mamedov Abasguly Guliyev 

机构地区：[1]Institute of Polymer Materials, Azerbaoan National Aeademy of Sciences, Azerbaijan

出　　处：《Journal of Chemistry and Chemical Engineering》2011年第9期832-840,共9页化学与化工（英文版）

摘　　要：By oxidative polycondensation of 1-naphthol and their copolycondensation with aniline or p-phenylenediamine the polyfucntional polyconjugated oligomers consisting of hydroxynaphthylene links have been prepared. These soluble and meltable oligomers showing thermostability, semiconducting and paramagnetic properties and also high reactivity at reactions characteristic for aromatic hydroxyl groups were used as active filler at preparation of rubbers from butyl and butadiene-nitrile rubbers. It has been shown that in partial or full substitution of carbon black by oligohydroxynaphthylenes or cooligohydroxynaphthylenephenylamines in composition of vulcanizate the prepared rubbers are characterized by noticeably high heat-physical, physical-mechanical and electrical properties （Pv = 10^8 - 10^6Om. cm ）.

关 键 词：NAPHTHOLS oligohydroxynaphthylenes polyfunctional polyconjugated oligomers electroconducting rubbers. 

分 类 号：TQ333.93[化学工程—橡胶工业] TQ534.9