巯基-乙烯基加成反应合成含硅聚合物的研究进展  

Research Progress of Silicon Containing Polymers by Thiol-ene Chemistry

作　　者：胡笛[1] 徐彩虹[1] 

机构地区：[1]中国科学院化学研究所,北京100190

出　　处：《高分子通报》2011年第10期111-119,共9页Polymer Bulletin

基　　金：科技部973计划(No.2010CB934705)

摘　　要：巯基-乙烯基加成反应具有清洁、高效、条件温和的特点,广泛应用于有机合成、聚合物科学和材料化学等诸多领域。国内外关于这一反应的研究已有大量文献报道,但该反应在含硅聚合物的合成与应用研究中还少有触及。本文综述了巯基-乙烯基加成反应在聚硅氮烷、聚硅碳烷、聚硅氧烷三种含硅聚合物合成中的应用,介绍了国内外的研究现状及发展趋势,并对硅基聚合物中的巯基-乙烯基加成反应的反应机理、动力学特征及其潜在应用领域进行了概述。The thiol-ene addition reaction applications in organic synthesis, polymer and about this reaction,but which has been used is a clean, efficient, robust and mild method with wide materials chemistry. Till now, there are a lot of references rarely in organosilicon and this micro-review summarizes the reports that describe the thiol-ene reactions and polysilazane. The mechanism, kinetics and were overviewed as well. of vinylsilanes prepared in polycarbosilane,polysiloxane its potential applications of thiol-ene addition reaction

关 键 词：巯基-乙烯基加成 含硅聚合物 合成 应用 

分 类 号：O634.41[理学—高分子化学]