[Cu_2(C_2O_4)(C_(12)H_8N_2)_2(C_3H_7NO)_2](ClO_4)_2配合物的合成及其热分解(英文)  

Synthesis and Thermal decomposition of μ-Oxalato-bis[(N,N′-dimethylformamide)(1,10-phenanthroline)copper(Ⅱ)]bis(perchlorate)

作　　者：刘慧[1,2] 徐寿相[1,2] 李艳飞[1,2] 汪海东[2] 

机构地区：[1]常州大学石油化工学院,江苏常州213164 [2]嘉兴学院生物与化学工程学院,浙江嘉兴314001

出　　处：《化学研究与应用》2011年第10期1405-1408,共4页Chemical Research and Application

基　　金：浙江省自然科学基金项目(Y4100780)资助;supported by the Natural Science Foundation of Zhejiang Province(Y4100780);the Foundation of Zhejiang Provincial Facilities and Information Infrastructure for Science and Technology

摘　　要：以邻菲罗啉、2,5二羟基-1,4-二噻烷和Cu(ClO4)2.6H2O为原料,合成了中心对称的双核配合物[Cu2(C2O4)(C12H8N2)2(C3H7NO)2](ClO4)2(1)。通过红外光谱、元素分析等分析测试手段对其进行了表征;借助TG-DTG技术在氮气气氛下研究了配合物的热分解情况,并根据热分析结果确定了其热分解机理。The title centrosymmetric binuclear complex,[Cu2（C2O4）（C12H8N2）2（C3H7NO）2]（ClO4）2（1）,was synthesized by the reaction of 1,10-phenanthroline,2,5-dihydroxy-1,4-dithiane and Cu（ClO4）2·6H2O.Then the complex was characterized by IR spectra and elemental analysis.The thermal decomposition of the complex was studied by TG technique under dynamic nitrogen atmosphere.The thermal decomposition mechanism of the complex has been determined on the basis of thermal analysis.

关 键 词：双核铜配合物 合成 热分解 

分 类 号：O641.4[理学—物理化学]