Synthesis and Characterization of Mesomorphic Behaviour of New Mesogenic Compounds Incorporating Cholesteryl Ester Moiety Connected to 1,3,4-Oxadiazole  

Synthesis and Characterization of Mesomorphic Behaviour of New Mesogenic Compounds Incorporating Cholesteryl Ester Moiety Connected to 1,3,4-Oxadiazole

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作  者:Ivan H. R. Tomi Maha T. S. Al-Mahdawi Isam A. Latif Fawwaz I. Khlili Ammar H. AI-Dujaili 

机构地区:[1]Department of Chemistry, College of Science, AI-Mustansiriya University, Baghdad, Iraq [2]Department of Chemistry, College of Education, Ibn AI-Haitham, University of Baghdad, Baghdad, Iraq [3]Department of Chemistry, Faculty of Science, University of Jordan, Amman, Jordan

出  处:《Journal of Chemistry and Chemical Engineering》2011年第10期946-955,共10页化学与化工(英文版)

摘  要:The synthesis and characterization of new series of liquid crystals containing cholesteryl moiety connected via an ester linkage to 1,3,4-oxadiazole are reported. The molecular structures of the intermediates and target compounds were confirmed by elemental analyses and FT-IR, ^1H NMR and mass spectrometry. The mesomorphic behaviors were investigated by polarizing optical microscopy (POM) attached with hot stage and differential scanning calorimetry (DSC). Enantiotropic smectic 1, smectic A, blue phase and cholesteric mesophases are exhibited by the newly synthesized compounds.

关 键 词:MESOMORPHIC 1 3 4-oxadiazole cholesteryl ester cholesteric phase smectic phase 

分 类 号:O626.2[理学—有机化学] Q513[理学—化学]

 

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