镍催化芳基-芳基交叉偶联反应的配体研究新进展  

New Progress in Nickel-Catalyzed Aryl-Aryl Cross-Coupling Reactions: A Ligand Survey

作　　者：李永清[1] 曹育才[1] 叶晓峰[1] 周慧[1] 

机构地区：[1]上海化工研究院,上海200062

出　　处：《有机化学》2011年第10期1538-1552,共15页Chinese Journal of Organic Chemistry

基　　金：上海市科委国际科技合作基金(No.10520707600)资助项目

摘　　要：联芳基结构在天然产物、药物以及各种光电材料中广泛存在,自20世纪70年代以来,各种过渡金属催化的芳基-芳基偶联手段得到普遍应用,配体、底物、辅助手段等的研究也快速发展.从配体类型的角度综述了镍催化的芳基-芳基交叉偶联反应.Biaryls widely exist in natural products,pharmaceuticals and various photoelectricity materials.Remarkable progress of cross-couplings has been achieved since the 70s of 20th century using a few transi-tion metals for the production of biaryls.Particular attentions are being focused on ligands,substrates and assistant techniques.Nickel-catalyzed aryl-aryl cross-coupling reactions are reviewed from the point of ligands.

关 键 词：镍 过渡金属催化 配体 联芳烃 交叉偶联 

分 类 号：O621.25[理学—有机化学]