Gemini阳离子烷基糖苷表面活性剂的合成及性能  

SYNTHESIS AND PROPERTY STUDY OF GEMINI CATIONIC ALKYL POLYGLUCOSIDES SURFACTANT

作　　者：朱红军 丁徽 牛华 娄平均 

机构地区：[1]河南省表面活性剂工程技术研究中心,河南郑州450002 [2]河南省道纯化工技术有限公司,河南郑州450002

出　　处：《精细石油化工》2011年第5期13-16,共4页Speciality Petrochemicals

基　　金：科技部中小企业创新基金项目(11C26214102442)

摘　　要：实验以非离子烷基糖苷(APG)制得的氯代糖苷与二乙胺反应生成糖苷基叔胺,然后再与1,2-二溴乙烷(EDB)进行季铵化反应而制得Gemini阳离子烷基糖苷表面活性剂。通过单因素实验和正交实验考察了反应的影响因素,确定Gemini阳离子烷基糖苷表面活性剂的优化工艺条件为:n(糖苷基叔胺)∶n(EDB)=2.2∶1,w(异丙醇)=50%,反应温度60℃,反应时间10h,收率达85.7%,其CMC为3.16×10-3 mol/L,γCMC为29.4mN/m,并且具有较低的Krafft点,亲水性较好。A Gemini cationic alkyl polyglucosides surfactant was synthesized from alkyl polyglucosides （APG）, diethylamine and 1,2-dibromoethane （EDB）. The effects on the reaction process were investigated by the single factor and orthogonally arranged experiments. The optimum conditions were obtained as follows, n （glycoside-based tertiary amine） ： n （EDB） = 2. 2 ： 1, w（isopropyl alcohol） = 50%, reaction temperature 60 ℃, reaction time 10 h, with the yield of 85.7%. The Gemini cationic alkyl polyglucosides surfactant has a good surface performance as follows. CMC=3.16×10^-3 mol/L, γCMC=29. 4 mN/m and low Krafft point.

关 键 词：烷基糖苷 氯代糖苷 1  2-二溴乙烷 双子阳离子烷基糖苷表面活性剂 

分 类 号：TQ423.12[化学工程]