Preparation of CeB_6 nano-powders by self-propagating high-temperature synthesis(SHS)  

作　　者：豆志河 张廷安 刘燕 郭永楠 赫冀成 

机构地区：[1]Key Laboratory for Ecological Utilization of Multimetallic Mineral(Ministry of Education),Northeastern University

出　　处：《Journal of Rare Earths》2011年第10期986-990,共5页稀土学报（英文版）

基　　金：supported by National Natural Science Foundation of China(51002025,50644016,50874027)

摘　　要：CeB6 powders were prepared by high-temperature self-propagating synthesis （SHS） in which CeO2, B203 and Mg were taken as reactants. The adiabatic temperature and dynamics of SHS reactions were investigated. The SHS reaction products and leached products were characterized by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The results indicated that the adiabatic temperature of Mg-B2Oa-CeO2 reaction system was rather higher than 1800 K to make the reaction propagate by itself, and the apparent activation energy （Ea） and reaction order （n） of exothermic peak on Mg-BzO3-CeO2 differential scanning calorimetry （DSC） curve were 23.03 kJ/mol and 1.31, respectively. The apparent activation energy was lower, so the reaction occurred easily. The SHS products consisted of MgO, CeB6 and little MgaB2O6. The leached products consisted of single CeB6 phase and its purity was higher than 99.0%, and the average particle sizes of CeB6 were smaller than 150 nm.CeB6 powders were prepared by high-temperature self-propagating synthesis （SHS） in which CeO2, B203 and Mg were taken as reactants. The adiabatic temperature and dynamics of SHS reactions were investigated. The SHS reaction products and leached products were characterized by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The results indicated that the adiabatic temperature of Mg-B2Oa-CeO2 reaction system was rather higher than 1800 K to make the reaction propagate by itself, and the apparent activation energy （Ea） and reaction order （n） of exothermic peak on Mg-BzO3-CeO2 differential scanning calorimetry （DSC） curve were 23.03 kJ/mol and 1.31, respectively. The apparent activation energy was lower, so the reaction occurred easily. The SHS products consisted of MgO, CeB6 and little MgaB2O6. The leached products consisted of single CeB6 phase and its purity was higher than 99.0%, and the average particle sizes of CeB6 were smaller than 150 nm.

关 键 词：SHS CeB6 NANO-POWDERS rare earths 

分 类 号：TB383.1[一般工业技术—材料科学与工程]