5-乙酰硫苯基-10,15,20-三苯基卟啉的合成和循环伏安性质研究  

Synthesis and cyclic voltammetry property of 5-Acetylthiophenyl-10,15,20-triphenylporphyrin

作　　者：李长恭[1] 尚静艳[1] 

机构地区：[1]河南科技学院,河南新乡453003

出　　处：《河南科技学院学报（自然科学版）》2011年第5期58-63,共6页Journal of Henan Institute of Science and Technology(Natural Science Edition)

基　　金：国家自然科学基金(21072046);河南科技学院高学历人才资助项目(08009)

摘　　要：合成了5-乙酰硫苯基-10,15,20-三苯基卟啉(AcS-TPP),用熔点、红外光谱、核磁共振表征了相关化合物的结构.用电化学循环伏安方法研究了5-乙酰硫苯基-10,15,20-三苯基卟啉及相关化合物5-甲硫基苯基-10,15,20-三苯基卟啉(CH3S-TPP)和5,10,15,20-四苯基卟啉(TPP)的循环伏安性质.The acetylthiophenylporphyrin was synthesized from p-methylthiobenzaldehyde,benzaldehyde and pyrrole.The structures of all the products were characterized by melting point,IR,and 1H-NMR.The cyclic voltammetry properties of acetylthiophenylporphyrin and related porphyrin were investigated by electrochemistry method.

关 键 词：卟啉 合成 结构表征 循环伏安 

分 类 号：O621.13[理学—有机化学]