具有选择性胶凝能力的小分子胶凝剂研究进展  

Progress in the Studies of Low-Molecular Mass Gelators with Phase-Selective Gelation Properties

作　　者：侯晓育 刘凯强[1] 房喻[1] 

机构地区：[1]应用表面与胶体化学教育部重点实验室陕西师范大学化学与材料科学学院,西安710062

出　　处：《应用化学》2011年第11期1221-1228,共8页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金(20773083;91027017)资助项目

摘　　要：不相溶混合溶剂的选择性胶凝对于溶剂纯化和分离,特别是溢油处理和水体净化具有十分重要的意义。具有选择性胶凝能力的胶凝剂可以是高分子、微纳米颗粒和小分子胶凝剂。然而,相对于高分子和微纳米颗粒材料,以小分子化合物为胶凝剂的凝胶往往具有凝胶-溶胶相变可逆性,这种可逆性无疑会对凝胶体系的实际应用带来额外的好处。基于这些考虑,本文按照胶凝剂分子的结构,分类介绍此类小分子胶凝剂研究进展,并展望了相关研究的前景和可能应用。Phase-selective gelation of mixed un-miscible solvents is of great importance considering its applications in purification and separation,particularly in the recovery of spilled oil and in the purification of water.Gelators with phase-selective gelation properties could be polymers,micro-nano-particles or lowmolecular mass gelators（LMMGs）.Compared with former two kinds of gelators,gelation using LMMGs as gelators is always reversible.Such reversibility could add additional advantages to practical applications of the gel systems.Progress in the studies of LMMGs with phase-selective gelation properties is reviewed according to the structures of the relevant gelators.Furthermore,prospectives of the studies and the potential applications of the phase-selective gelation phenomenon are also presented.

关 键 词：小分子胶凝剂 选择性胶凝 散油回收 水净化 

分 类 号：O548.1[理学—物理]