两种新的噁嗪类化合物的合成与结构表征  

Synthesis and structural characterization of two new oxazine compounds

作　　者：岳荣耀[1] 李陵岚[1] 叶楚平[1] 

机构地区：[1]湖北大学化学化工学院,湖北武汉430062

出　　处：《化学试剂》2011年第11期1049-1050,1053,共3页Chemical Reagents

摘　　要：利用2-萘肼和对氯苯肼盐酸盐经Fisher法合成了4,5-苯并-2,3,3-三甲基-3-氢吲哚和5-氯-2,3,3-三甲基-5-氢吲哚,合成的吲哚分别与2-氯甲基-4-硝基苯酚反应合成了两个结构新颖未见报道的光致变色化合物,并通过NMR、IR、质谱对目标化合物的结构进行鉴定。The 4,5-benzo-2,3,3-trimethyl-3-hydrogen indole and 5-chloro-2, 3,3-trimethy-5H-indole was synthesized by Fisher method according 2-naphthalene and chlorobenzene hydrazine hydrochloride. The novel oxazine compounds which have not been reported by indole and 2-chloromethyl-4-nitrophenol was synthesized. The structure of the target product was confirmed by NMR,MS and IR.

关 键 词：4 5-苯并-2 3 3-三甲基-3-氢吲哚 5-氯-2 3 3-三甲基-5-氢吲哚 噁嗪 合成 

分 类 号：O621.3[理学—有机化学]