检索规则说明:AND代表“并且”;OR代表“或者”;NOT代表“不包含”;(注意必须大写,运算符两边需空一格)
检 索 范 例 :范例一: (K=图书馆学 OR K=情报学) AND A=范并思 范例二:J=计算机应用与软件 AND (U=C++ OR U=Basic) NOT M=Visual
作 者:安琳[1] 王晨[1] 张玲[1] 薛运生[1] 牟杰[1]
出 处:《化学试剂》2011年第11期1051-1053,共3页Chemical Reagents
摘 要:在微波辐射条件下,以对叔丁基杯[6]、杯[8]芳烃为原料,采用氯化苄、碘代正丁烷、溴代正戊烷为烃基化试剂,PEG-400为催化剂,制备了标题化合物,通过IR、1HNMR光谱对产物的结构进行表征。微波辐射约5 min,即可得到收率中等(40%~66%)的对叔丁基杯芳烃O-烃基化衍生物。结果表明微波辐射法操作简单、反应时间大大缩短、污染明显减少。To probe into the feasibility of efficiently synthesi- zing O-alkylated ealix[ n ] arene derivatives. Under microwave irradiation condition, six fully O-aikyiated calix[ n] arene derivatives were efficiently synthesized by using p-tert-butylca]ix [ n ] arenes ( n = 6,8 ) with some alkylating reagents such as benzyl chloride, 1-iodobutane, 1-bromopentane. Structures of those compounds were also characterized by the IR and ^1HNMR. The reaction time was about 5 min. the moderate yields of from 40% to 60% were obtained. The results showed the method of microwave irradiation for the preparation of functional O-alkyated calix [ n ] arene derivatives was simple, efficient and reaction time-saving.
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在链接到云南高校图书馆文献保障联盟下载...
云南高校图书馆联盟文献共享服务平台 版权所有©
您的IP:216.73.216.124