高分子铱配合物磷光材料的制备技术进展  

Technical development in the synthesis of polymer iridium complex electrophosphorescent materials

作　　者：郭远辉[1,2] 王玲霞[1,2] 翁洁娜[1,2] 颜芳[1,2] 梅群波[1,2] 黄维[1,2] 

机构地区：[1]有机电子与信息显示国家重点实验室培育基地,南京210046 [2]南京邮电大学信息材料与纳米技术研究院,南京210046

出　　处：《科学通报》2011年第31期2548-2560,共13页Chinese Science Bulletin

基　　金：国家自然科学基金青年科学基金(50803027;50903001和20905038);江苏省高校自然科学基础研究面上项目(08KJD430020);江苏高校优秀创新团队(TJ207035);国家重点基础研究发展计划(2009CB930600)资助

摘　　要：电致磷光材料因其优异的发光性能,引起了人们广泛关注.铱配合物是研究最多的电致磷光材料,高分子化的铱配合物由于加工方便、成膜性好等优点成为最近研究的重点.本文从合成的角度出发,介绍了含配位基团的高分子配体和含铱的二氯桥小分子铱配合物作用、小分子铱配合物烯类单体的自聚及与其他单体的共聚、开环易位聚合、接枝、溶胶凝胶法等制备高分子化铱配合物的方法,并概述了这些制备方法对器件发光性能的影响.Electrophosphorescent materials and their excellent properties have attracted significant attention because of their potential application as highly efficient electroluminescent emitters in organic light emitting diodes （OLEDs）. Iridium （III） complexes were selected as optimal materials for electrophosphorescent material synthesis as their strong spin orbit coupling may result in high luminescence efficiencies, a short excited-state lifetime and excellent color change from blue to the near-infrared region. Polymer iridium complex electrophosphorescent materials combine the processing properties of polymers and the optical properties of the small molecule iridium （III） complexes and were used with ease in the fabrication of large-scale structures in OLEDs by spin-coating. Several important syntheses methods of these polymer metal complexes are reviewed in this article. Furthermore, the merits and demerits of these methods are also discussed. Finally, synthesis problems were highlighted and some perspectives were proposed for future study.

关 键 词：铱配合物 高分子磷光材料 制备技术 有机电致发光器件 发光效率 

分 类 号：TN104.3[电子电信—物理电子学]