交联共聚物(ER-PEO)及其与NaSCN络合物的结构研究  

STRUCTURAL STUDY OF CROSSLINKED COPOLYMERS(ERPEO)AND THEIR COMPLEXES WITH SODIUM THIOCYANATE

作　　者：张宏放[1] 莫志深[1] 彭新生[1] 王佛松[1] 

机构地区：[1]中国科学院长春应用化学研究所,长春130022

出　　处：《应用化学》1990年第1期62-65,共4页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金

摘　　要：环氧树脂(ER)与聚环氧乙烷(PEO)的共混物经水/乙醇萃取后的剩余物为交联ER-PEO非晶共聚物。萃取分析表明,ER/PEO中约有50wt·％的PEO与ER形成ER-PEO交联共聚物。ER/PEO与NaSCN络合后,由于Na^+的配位络合作用,使结晶能力进一步降低。The structure of the crosslinked copolymers(and/or blends) of epoxy resin/polyethyleneoxide (ER/PEO) and their complexes with sodium thiocyanate after extraction has beenstudied by using WAXD, SAXS, DSC and SEM methods. The r?sults showed that thesamples after extraction have an amorbhous structures of the crosslinked copolymers (ER-PEO). The crystallinity of the complexes ER/PEO-NaSCN was decreased as compared withcorresponding blends ER/PEO, due to the presence of Na ion.

关 键 词：固体电解质 交联共聚物 ER-PEO 

分 类 号：TM242[一般工业技术—材料科学与工程]